Category Archives: Gas Processing

Compressor Calculations: Rigorous Using Equation of State vs Shortcut Method

Written on November 1, 2011 at 6:30 am, by

In this tip of the month (TOTM) we will present the compressor calculations of a case study. We will compare the rigorous method results with the values from the short cut methods. The rigorous method is based on an equation of state like the Soave-Redlich-Kwong (SRK) for calculating the required enthalpies and entropies. The enthalpiesContinue Reading

Liquid Density by Volume Translated Method – Part 3: Light Hydrocarbon Mixtures

Written on October 1, 2011 at 6:00 am, by

In the March 2011 tip of the month (TOTM) we studied a constant volume translation of liquid density method presented by Peneloux et al. [3] and demonstrated its application for pure components. Considerable improvements were obtained, specifically for the low temperature range (reduced temperature < 0.8), of saturated specific volume (or liquid density) predicted byContinue Reading

A Simple Model for Estimation of Methanol Loss to Vapor Phase

Written on August 1, 2011 at 9:59 am, by

As discussed in the May 2011 Tip Of The Month (TOTM), for hydrate inhibition, the most commonly used equilibrium inhibitors used in the upstream and midstream sectors of the oil and gas business are:  monoethylene or diethylene glycol (MEG or DEG) and methanol.  In general, glycols are more commonly used in systems requiring continuous inhibition.Continue Reading

Liquid Density by Volume Translated Method – Part 2: Recent Development

Written on July 1, 2011 at 12:03 pm, by

Equations of state (EoS) are used in commercial simulation software for predicting phase behavior and thermodynamic properties. The cubic equations of state (EoS) give relatively accurate results for predicting vapor-liquid equilibria, especially for non-polar or slightly polar systems. Furthermore, these equations can be used to accurately predict vapor densities, enthalpy and entropy. These advantages encourageContinue Reading

Absorption of Aromatics Compounds (BTEX) in TEG Dehydration Process

Written on June 1, 2011 at 8:33 am, by

BTEX stands for benzene, toluene, ethylbenzene, and xylene, a group of compounds all that also belong to the broader category of Hazardous Air Pollutants (HAPs). Benzene is a known carcinogen, and has also been shown to cause blood disorders and to impact the central nervous system and the reproductive system.  Toluene may affect the reproductive and central nervousContinue Reading

Estimation of Methanol Loss to Vapor Phase

Written on May 1, 2011 at 6:00 am, by

Three methods of preventing hydrate formation in pipelines and processing facilities are commonly used in our industry.  These are: 1)      Maintain the T & P of the system outside of the hydrate formation region. 2)      Dehydrate the gas to remove the water. 3)      Inhibit hydrate formation with chemical inhibitors. Option 3 is commonly used whenContinue Reading

Liquid Density by Volume Translated Method – Part 1: Pure Compound

Written on March 1, 2011 at 10:47 pm, by

Liquid density is needed for process simulation and equipment design. For example, accurate predictions of liquid density are needed for calculating the pressure drop in piping/pipeline and vessel sizing. Accurate liquid density is also essential for custody transfer. In November 2006, December 2006 and January 2007 tips of the month (TOTM), we presented an overviewContinue Reading

What is the Impact of Water Content on the Dew Point and Hydrate Phase Behavior?

Written on January 1, 2011 at 10:34 pm, by

In a past Tip Of The Month (TOTM), we have shown that one of the first issues to be resolved by a facilities engineer working in a gas plant or gas production facility is where the process is operating with respect to the phase diagram.  A general knowledge, if not a detailed knowledge, will allowContinue Reading

Should the TEG Dehydration Unit Design Be Based on the Water Dew Point or Hydrate Formation Temperature?

Written on December 1, 2010 at 10:27 pm, by

Glycol dehydration is the most common dehydration process used to meet pipeline sales specifications and field requirements (gas lift, fuel, etc.). Triethylene glycol (TEG) is the most common glycol used in absorption systems. Chapter 18, Gas Conditioning and Processing [1] presents the process flow diagram and basics of glycol units. A key parameter in sizingContinue Reading

Process Analysis of Hydrogen Blistering in NGL Fractionation Unit

Written on November 1, 2010 at 10:25 pm, by

Hydrogen blistering is a type of hydrogen-induced failure produced when hydrogen atoms enter low-strength steels that have macroscopic defects, such as laminations. The defects in the steel (void spaces) provide places for hydrogen atoms to combine, forming gaseous molecular hydrogen (H2) that can build enough pressure to produce blistering. Hydrogen blistering is a problem mainly inContinue Reading